Developing sustainable lignin-based non-isocyanate polyurethane (NIPU) foams for building insulation, featuring high R-value and fire resistance. This eco-friendly solution leverages lignin's natural properties to eliminate toxic isocyanates from the production process.
The proposed solution focuses on creating a sustainable alternative to conventional polyurethane (PU) foam insulation by utilizing lignin, a carbon-negative and structurally compatible polyol resource. This eco-friendly foam insulation offers enhanced thermal performance and robust fire resistance, making it ideal for modern building applications. By synthesizing non-isocyanate polyurethane (NIPU) foams, the technology aims to achieve a high R-value of over 7 per inch, addressing the need for efficient insulation in space-limited areas while meeting Class A fire performance standards.
Lignin, an inherently hydrophobic and fire-resistant material, is chemically modified through a three-step process: oxyalkylation, transesterification, and polyaddition. This process results in cyclic carbonate-functionalized lignin, which reacts with a bio-based diamine to form crosslinked NIPU foam. Key features include:
Currently at TRL 3, this technology has undergone initial laboratory validation, demonstrating its potential for scale-up. Future work will focus on optimizing production conditions and characterizing the chemical structure, thermal, flammability, and mechanical properties of the foam to ensure readiness for commercial applications.
UT offers a partnership model that reduces risk, accelerates time-to-value, and supports long-term growth strategies for industry—providing an attractive platform for companies seeking to formalize collaboration and establish a long-term presence in the East Tennessee region. By aligning institutional investment with regional and national priorities, UT provides a stable and effective platform for industry collaboration, technology deployment, and sustained economic impact.