Eco-friendly carbon-storing foam insulation with enhanced thermal performance

Technology
Conceptual
University

Developing sustainable lignin-based non-isocyanate polyurethane (NIPU) foams for building insulation, featuring high R-value and fire resistance. This eco-friendly solution leverages lignin's natural properties to eliminate toxic isocyanates from the production process.

Overview

The proposed solution focuses on creating a sustainable alternative to conventional polyurethane (PU) foam insulation by utilizing lignin, a carbon-negative and structurally compatible polyol resource. This eco-friendly foam insulation offers enhanced thermal performance and robust fire resistance, making it ideal for modern building applications. By synthesizing non-isocyanate polyurethane (NIPU) foams, the technology aims to achieve a high R-value of over 7 per inch, addressing the need for efficient insulation in space-limited areas while meeting Class A fire performance standards.

Technical specifications

Lignin, an inherently hydrophobic and fire-resistant material, is chemically modified through a three-step process: oxyalkylation, transesterification, and polyaddition. This process results in cyclic carbonate-functionalized lignin, which reacts with a bio-based diamine to form crosslinked NIPU foam. Key features include:

  • Elimination of toxic isocyanates in foam production
  • Use of aminated lignin that reacts with bicyclic carbonates for NIPU synthesis
  • Enhanced fire resistance due to lignin's natural charring behavior
  • Compatibility with existing building materials for easy integration
Technology readiness level

Currently at TRL 3, this technology has undergone initial laboratory validation, demonstrating its potential for scale-up. Future work will focus on optimizing production conditions and characterizing the chemical structure, thermal, flammability, and mechanical properties of the foam to ensure readiness for commercial applications.


About University of Tennessee, Knoxville

UT offers a partnership model that reduces risk, accelerates time-to-value, and supports long-term growth strategies for industry—providing an attractive platform for companies seeking to formalize collaboration and establish a long-term presence in the East Tennessee region. By aligning institutional investment with regional and national priorities, UT provides a stable and effective platform for industry collaboration, technology deployment, and sustained economic impact.

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