We have developed a novel extension of electrochemistry that enables real-time monitoring of catalysis/catalyst in-situ and -operando. As a demonstration, we have used Ag as a catalyst and monitored breakdown of H2O2. Our method/apparatus enables for the first time real time kinetics measurements of various intermediate Ag-oxygen species that are formed and consumed as products are formed. This is a platform method/apparatus that can be used to advance catalyst develop efficiently.
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