Solvent-assisted thermo-catalytic conversion of HDPE-PCR to waxes

Technology
Conceptual
University

Innovative conversion process transforming high-density polyethylene waste into valuable waxes using metal-halide catalysts. This method improves efficiency by lowering operational temperatures and reaction times, offering a sustainable solution for plastic waste recycling.

Overview

The proposed solution is a novel solvent-assisted thermo-catalytic process designed to convert high-density polyethylene (HDPE) post-consumer resin (PCR) into waxes and other valuable hydrocarbons. This method addresses the limitations of traditional catalytic processes that rely on precious metals by utilizing metal-halide catalysts, reducing both operational temperatures and reaction times. This approach not only promotes the sustainable recycling of plastic waste but also generates valuable by-products that can serve as solvent resources for further reactions.

Technical specifications

Key features:

  • Utilizes metal-halide catalysts such as NaCl, KCl, and MgCl2 to facilitate HDPE deconstruction.
  • Operates at reduced temperatures (300-425°C) and shorter reaction times (1-4 hours).
  • Employs a slurry of metal halide and high molecular weight wax to enhance mass transfer.
  • Produces waxes with controlled molecular weight profiles and reduced polydispersity.
  • Investigates recyclability of catalysts and by-products to enhance process sustainability.
Technology readiness level

This technology is at TRL 3, indicating that it has been demonstrated analytically and experimentally at a laboratory scale. Future validation plans include optimizing reaction conditions, performing techno-economic analysis, and exploring catalyst recyclability and by-product utilization.


About University of Tennessee, Knoxville

UT offers a partnership model that reduces risk, accelerates time-to-value, and supports long-term growth strategies for industry—providing an attractive platform for companies seeking to formalize collaboration and establish a long-term presence in the East Tennessee region. By aligning institutional investment with regional and national priorities, UT provides a stable and effective platform for industry collaboration, technology deployment, and sustained economic impact.

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