Time Domain NMR for rapid assessment of adhesive and coating molecular mobility

Facilities & testing
Company

This solution utilizes Time Domain NMR (TD-NMR) to evaluate molecular mobility in adhesives and coatings, linking these metrics to performance. It offers insights into molecular dynamics during adhesive setting, enhancing formulation and application processes.

Overview

Time Domain NMR (TD-NMR) offers a novel approach for rapidly assessing the molecular mobility of components within adhesives and coatings. This solution bridges the gap between molecular dynamics and performance, providing real-time insights into the setting processes of coatings and the fibril formation in pressure-sensitive adhesives. The ability to measure and analyze molecular motion through TD-NMR can significantly enhance the understanding and development of high-performance adhesive products.

Technical specifications

Key features:

  • Utilizes TD-NMR to quantify molecular mobility, providing insights into cross-link formation and solvent evaporation in coatings.
  • Analyzes molecular dynamics in pressure-sensitive adhesives to assess fibril formation.
  • Employs Multiple Quantum methods for detailed evaluation of entangled and crosslinked systems.
  • Initial validation involves measuring NMR relaxometric parameters such as T1, T2, and multiple quantum coherence.
  • Use of microparticle reference samples accelerates data collection by maximizing surface/volume ratio.
Technology readiness level

The technology is currently at Technology Readiness Level 4. Initial validation has been conducted, with ongoing efforts to refine data collection and analysis methods to suit various adhesive and coating formulations.


About Graftonica

Graftonica is an Italian spin-off company of the University of Milano-Bicocca established in 2015 that specializes in materials science, with a primary focus on polymers, composites, and nanotechnology. The company develops and markets nanotech additives designed to improve the functional performance of rubber and plastics. Their core methodology, inspired by the lab-on-a-particle concept, centers on the compatibilization and dispersion of inorganic nanofillers within polymer matrices. This approach allows for the creation of smart materials with tailored properties, such as high dielectric constants for electronics, improved barrier performance for food packaging, and specialized optical or biocompatible characteristics. The company operates from laboratories within the University's Department of Materials Science.

Beyond product development, Graftonica provides a comprehensive suite of technical services to industrial and academic partners. These include detailed material characterization, analysis and deformulation of existing materials, failure analysis, and the prototyping of custom materials. By leveraging advanced research expertise and scientific instrumentation, the team supports clients in enhancing their production processes, conducting quality control, and scaling up chemical reactions from literature. Their work serves various sectors, including manufacturing, electronics, and the restoration of cultural heritage, aiming to provide sustainable and innovative solutions that bridge the gap between advanced academic research and industrial application.

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