University of Minnesota

Zeolite-coated novel materials for enhanced biological nitrogen removal from water

Technology
Conceptual
University

Novel zeolite-coated hollow fiber membranes and porous polymer disks that adsorb ammonium and create a niche for anammox bacteria, enabling total biological nitrogen removal from wastewater and stormwater. Developed and lab-validated at the University of Minnesota.

Overview

Nitrogen pollution in water is a persistent environmental challenge, and conventional treatment approaches often struggle to achieve complete biological nitrogen removal. This solution introduces novel materials—hollow fiber membranes and porous polymer disks coated in zeolite—that adsorb ammonium from water and create an ideal microenvironment for anaerobic ammonia oxidizing (anammox) bacteria. By enriching for anammox populations, these materials enable the conversion of total nitrogen into harmless dinitrogen gas, offering a more efficient and sustainable approach to nitrogen removal in both wastewater and stormwater applications.

Technical specifications
  • Zeolite-coated hollow fiber membranes that adsorb ammonium from solution, even in complex wastewater matrices, and preferentially support colonization by anammox bacteria
  • Gas-transfer capability of the membranes enables controlled aerobic ammonia oxidation alongside anammox activity
  • Porous polymer disks coated in zeolite that provide a lightweight, permeable packing material for deployment in stormwater retention zones
  • Polymer disks designed for use in low ammonium, moderate carbon wastewater environments where limited ammonia oxidation occurs
  • Flow-through reactor compatibility allowing the disks to be evaluated for anammox colonization, retention, and activity under synthetic stormwater conditions
  • Comparison testing against no-zeolite control disks to validate the specific contribution of the zeolite coating
Technology readiness level

The hollow fiber membranes have been extensively tested in the laboratory and have demonstrated preferential enrichment of anammox bacteria and improved total nitrogen removal. The porous polymer disks are currently undergoing laboratory testing to evaluate their capacity to facilitate anammox colonization and retention in low ammonium, moderate carbon wastewater. Future validation will expand testing to stormwater environments using flow-through reactors to monitor anammox colonization, total nitrogen loss, and bacterial retention over time. The technology is at an early-to-mid stage of development with promising laboratory results and planned expanded validation.


About University of Minnesota

The University of Minnesota is a flagship, comprehensive public research university spanning multiple campuses, with a large research enterprise and clinical integration. Industry engages through co-located labs on the Twin Cities campuses, access to an academic health system for clinical translation, and pilot and field-testing facilities that speed scale-up. A statewide extension network and outreach centers provide real-world sites and data partnerships across Minnesota, while proximity to a dense medtech and Fortune 500 corridor enables frequent collaboration. Research is supported by competitive federal funding, including NIH, NSF, DOE, USDA, and DoD. A dedicated technology transfer office manages IP, licensing, sponsored research agreements, and startup incubation to speed commercialization.

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