Bio-based tannin-furanic foams and polylactide beads as sustainable alternatives to expanded polystyrene

Technology
In development
University

Sustainable rigid foam technology using renewable tannin and furfuryl alcohol, plus polylactide bead foams, offering eco-friendly replacements for expanded polystyrene in packaging applications.

Overview

This research presents two sustainable alternatives to expanded polystyrene (EPS) for packaging and insulation applications. The first approach uses tannin-furanic rigid foams made from renewable tannin extract (a forestry and agricultural waste product) combined with furfuryl alcohol derived from furfural, a natural compound obtained through hydrolysis of sugars. The second approach uses polylactide (PLA) bead foams, a biopolymer sourced from renewable resources such as corn starch or sugarcane, processed using supercritical carbon dioxide as a blowing agent. Both solutions address growing demand for cost-effective, eco-friendly packaging materials that reduce reliance on petroleum-based polystyrene.

Technical specifications

Tannin-furanic rigid foams:

  • Formed through reaction of tannin, furfuryl alcohol, and formaldehyde water solution in a water medium
  • Tween 85 used as surfactant; p-toluene sulfonic acid as catalyst
  • Approximately 20% of final foam weight derived from furfuryl alcohol
  • Average bulk density measured at 0.070 g/cm³
  • Compressive strength of 0.07 MPa, improvable with zinc chloride additive
  • n-pentane proposed as a less toxic alternative blowing agent to diethyl ether
  • Porous structure confirmed through SEM imaging

Polylactide bead foams:

  • Produced using supercritical CO₂ extrusion foaming
  • Epoxy-based chain extender applied to improve foaming ability
  • Bead formation confirmed through visual observation and SEM analysis
  • Carbon dioxide serves as environmentally benign blowing agent

Key benefits:

  • Renewable feedstock reduces dependence on petroleum-based materials
  • Potential cost-effectiveness through use of waste-derived tannin
  • Biodegradable or bio-based end products
  • Comparable structural performance to EPS for packaging applications
Technology readiness level

The technology is currently at laboratory-scale validation stage. Foam formation has been confirmed through visual observation and FTIR analysis, with porosity and mechanical properties measured for prepared samples. The tannin-furanic foams have demonstrated structural integrity during manipulation with confirmed porous morphology. Future work includes optimizing mechanical, thermal, and morphological properties, scaling production, and conducting real-environment testing in the packaging industry. The research team seeks industry collaboration to refine cost-effectiveness, test additional bio-based material formulations, and accelerate commercial readiness within approximately one year of development.


About University of Novi Sad

The University of Novi Sad is a comprehensive public research university and one of the largest in Serbia, combining broad academic breadth with an applied research culture. Industry engagement is enabled by co‑located labs and a research and technology park that links faculty, students, startups, and corporate tenants. Integration with a major teaching hospital supports clinical studies and translational collaborations, while proximity to a dynamic regional ICT and agri‑food economy provides ready access to talent and pilot environments. Research is supported by competitive European programs and national funding, alongside industry‑sponsored contracts. A dedicated technology transfer office manages IP, licensing, and startup formation, with liaison services that streamline collaboration agreements.

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