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Biodegradable chelating agents selective for ferric ion
  • Background
  • What we're looking for
  • What we can offer you
  • Who we are
  • Q&A
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Background

Metal chelation is an essential mechanism for many household and industrial cleaning scenarios. In laundry, a wide range of strongly coloured stains derive their colour from metal complexes which are present within the stains. Chelating the metals within these stain complexes, effectively removing them from the stain, removes the stain colour and is one of the main mechanisms of effective detergency. Furthermore, heavy metals can accumulate on fabrics, causing damage to the fibre structure over time, and reducing the effectiveness of other cleaning ingredients, such as oxidising agents (hydrogen peroxide) that suffer from metal-catalysed decomposition mechanisms. Effectively chelating these metals therefore, contributes to overall detergent performance. 

 

Some of the most prevalent chelators used in detergent products belong to the phosphonates class, including etidronic acid (HEDP) and DTPMP (diethylenetriamine penta(methylenephosphonic acid)). These non-biodegradable materials are used broadly across many industries (pharmaceuticals, detergents, water treatment, and cosmetics). There is a critical need to find biodegradable chelants which can match their performance in terms of ferric ion (Fe(III)) chelation.

What we're looking for

We are looking for biodegradable chelating agents that can effectively replace non-biodegradable phosphonates, such as HEDP and DTPMP, while demonstrating strong performance in chelating Fe(III) in detergent formulations.

Solutions of interest include:
  • Biodegradable chelants
Our must-have requirements are:
  • Deprotonated at typical detergent solution pH (≤10).

  • High specificity for Fe(III): log K (β110) Fe (III) >10

  • Low specificity for Ca2+: log K (β110) Ca2+ <5

What's out of scope:
  • Biodegradable materials which are already known for use in detergents, such as methylglycinediacetic acid (MGDA), glutamic acid diacetic acid (GLDA), ethylenediamine-N,N'-disuccinic acid (EDDS), iminodisuccinic acid (IDS), hydroxyethyliminodiacetic acid (HEIDA), gluconate, glucarate
  • Known pharmaceutically-active iron chelators (e.g., deferoxamine, deferiprone, and deferasirox)
  • Hydroxypyridinones
  • Natural siderophores
  • We don’t want to receive any confidential information
Acceptable technology readiness levels (TRL):
Levels 1-9
What we can offer you
Eligible partnership models:
Supply/purchaseLicensingSponsored research
Benefits:
Sponsored Research
Funding is depended on the scope of work.
Who we are

At P&G, innovation is what we do best. We love finding solutions to problems. With the heart of a start-up and the resources of a global corporation, we are always looking for ways to reinvent every aspect of our business. As we innovate, we find inspiration in people - their needs, values, desires, and passions. The people of P&G R&D know that collaboration is key to unlocking visionary thinking. Our experts seamlessly work together with our external partners in the pursuit of the new, the next, the impossible. Read more here: https://www.pgconnectdevelop.com/

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Reviewers
Q&A with Procter & Gamble

The Q&A is now closed.

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Q.
Will the use of biodegradable surfactant will be of interest? Please let me know. We have more than 20 years of expertise in synthesis, characterization and application of these surfactants. Many thanks
3
Q.
Are glucarates ruled out for technical inadequacy, NOx emissions or economics? We can significantly reduce manufacturing cost for this glucaric acid and eliminate NOx production.
1
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